History of the Earth

Epitaxy

History of the Earth

Show Notes

Epitaxy, from Greek words meaning “upon” or “above” and “ordered arrangement,” in minerals means crystals of one (or the same) mineral growing in a particular crystallographic position on another (or the same) mineral. It happens because the molecular spacings and orientations happen to be similar, allowing, even encouraging the crystal structure of the second, later mineral to mesh with that of the first. Some mineralogists might say that epitaxy requires the two minerals to be different minerals, but I do not – just two distinct generations of crystallization.

My example here is calcite, calcium carbonate – the sharp brown crystals are rhombohedrons, and the stuff is probably brown because it may be slightly iron-bearing (but it’s not siderite, iron carbonate). The clear crystals sit preferentially upon the corners of the rhombohedrons. I’m pretty sure, but because calcite makes a myriad of crystal forms I’m not certain, that the rhombohedral corner of the brown crystals represents the basal pinacoid position in those crystals, and the complex saucer-like colorless second-generation crystals are poised there on their own basal pinacoids. The two pinacoid surfaces have the same molecular geometry, so the two different generations of crystals – brown and colorless – joined there.

The colorless crystals show a bunch of different forms, prisms, rhombohedrons, and probable scalenohedrons, along with the likely pinacoids.

This is all in a geode about 5 centimeters across, from Mt. Sterling, Illinois. The little crystals in the photo enlargements are about 1.5 millimeters across. I actually have both halves of this geode, although they were acquired from different dealers at different mineral shows a year or so apart.

Epitaxy isn’t especially unusual in the mineral world, but unless the minerals are in a particular crystallographic orientation, we’d probably just call one mineral growing on another an encrustation, or overgrowths or some similar word.

—Richard I. Gibson

More from History of the Earth

May 30, 2019

The mineral here is just calcite (even though it’s mostly almost black), but it shows interesting features. Cone-in-cone structures are nested cones, seen here in cross section. The inset shows them a little better – in the main photo, they are represented by very narrow vertical triangles.

May 27, 2019

Mineral Monday + Tectonic Tuesday. Blue quartz is uncommon and is usually colored by inclusions of unusual minerals like crocidolite, tourmaline, or dumortierite. The purplish-blue quartz here, from north of Llano, Texas, is colored by inclusions of ilmenite (iron-titanium oxide). This rock is called llanite for its occurrence in the Llano Uplift of central Texas, and although similar rocks are found in other parts of the world, the variety name llanite really only applies to this location. On a sunny day, the blue quartz in the rocks has an opalescent sheen that sometimes seems to “wink” at you from the outcrop.

May 21, 2019

Middle section of the 38-inch cross-section

May 17, 2019

In the far northwest corner of the flat, flat Texas panhandle, extending into New Mexico, there’s a narrow, elongate magnetic low. The intensity of the anomaly – 250 nanoTesla or more – says it’s fundamentally the expression of a lithologic change rather than a structure; i.e. it represents something pretty strongly magnetic. Its long narrow geometry is that of a dike. And its negative value suggests that it’s reversely polarized, solidifying from magma during a time when the earth’s magnetic field was in the orientation opposite to that today.

May 15, 2019

Thule was the far north in Greek and Roman literature, often identified with Scandinavia. Thursday was named after Thor, the Norse god of thunder. Whether these pink minerals are orthorhombic thulite or monoclinic clinothulite would take analysis that I haven’t done, but either way they contain trivalent manganese to give the pink color.

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